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- Non-random_two-liquid_model abstract "The non-random two-liquid model (short NRTL equation) is an activity coefficient model that correlates the activity coefficients of a compound i with its mole fractions in the liquid phase concerned. It is frequently applied in the field of chemical engineering to calculate phase equilibria. The concept of NRTL is based on the hypothesis of Wilson that the local concentration around a molecule is different from the bulk concentration. This difference is due to a difference between the interaction energy of the central molecule with the molecules of its own kind and that with the molecules of the other kind . The energy difference also introduces a non-randomness at the local molecular level. The NRTL model belongs to the so-called local-composition models. Other models of this type are the Wilson model, the UNIQUAC model, and the group contribution model UNIFAC. These local-composition models are not thermodynamically consistent due to the assumption that the local composition around molecule i is independent of the local composition around molecule j. This assumption is not true, as was shown by Flemmer in 1976.".
- Non-random_two-liquid_model thumbnail Vapor-Liquid_Equilibrium_of_the_Mixture_of_Chloroform_and_Methanol_NRTL_Fit_and_Extrapolation_to_Different_Pressures.png?width=300.
- Non-random_two-liquid_model wikiPageID "14053488".
- Non-random_two-liquid_model wikiPageRevisionID "604344404".
- Non-random_two-liquid_model hasPhotoCollection Non-random_two-liquid_model.
- Non-random_two-liquid_model subject Category:Physical_chemistry.
- Non-random_two-liquid_model subject Category:Thermodynamic_models.
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- Non-random_two-liquid_model comment "The non-random two-liquid model (short NRTL equation) is an activity coefficient model that correlates the activity coefficients of a compound i with its mole fractions in the liquid phase concerned. It is frequently applied in the field of chemical engineering to calculate phase equilibria. The concept of NRTL is based on the hypothesis of Wilson that the local concentration around a molecule is different from the bulk concentration.".
- Non-random_two-liquid_model label "Non-Random-Two-Liquid-Modell".
- Non-random_two-liquid_model label "Non-random two-liquid model".
- Non-random_two-liquid_model sameAs Non-Random-Two-Liquid-Modell.
- Non-random_two-liquid_model sameAs m.03cs5w2.
- Non-random_two-liquid_model sameAs Q1996101.
- Non-random_two-liquid_model sameAs Q1996101.
- Non-random_two-liquid_model sameAs Non-random_two-liquid_model.
- Non-random_two-liquid_model wasDerivedFrom Non-random_two-liquid_model?oldid=604344404.
- Non-random_two-liquid_model depiction Vapor-Liquid_Equilibrium_of_the_Mixture_of_Chloroform_and_Methanol_NRTL_Fit_and_Extrapolation_to_Different_Pressures.png.
- Non-random_two-liquid_model isPrimaryTopicOf Non-random_two-liquid_model.