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- Oxatriquinane abstract "Oxatriquinane is an alkyl oxonium ion with formula C9H15O+, remarkable for being stable in aqueous solution. It has a cyclononane backbone, with the trivalent oxygen connected to carbons 1,4, and 7, forming three fused pentagonal cycles.Oxonium ions normally are strong alkylating agents and are only observed in solution as reactive intermediates or under extreme conditions. Oxatriquinane does not react with boiling water or with alcohols, thiols, halide ions, or amines, although it does react with stronger nucleophiles such as hydroxide, cyanide, and azide. It also had the longest C−O bond and more acute C−O−C angles yet seen in oxonium compounds.Oxatriquinane was first described in 2008, and was obtained after a five-step synthesis starting from cyclononatriene. The same paper also described oxatriquinacene, the tri-unsaturated analog, which is of interest as a possible precursor to oxaacepentalene, a neutral aromatic species. A methylated derivative, 1,4,7-trimethyloxatriquinane, was described in the same year. It is stable in solution in methanol, chloroform, and under refluxing in ethanol, and was crystallized as the PF−6 salt.".
- Oxatriquinane iupacName "(2as,4as,6as)-Octahydro-1H-2a1-oxacyclopenta[cd]pentalen-2a1-ium".
- Oxatriquinane thumbnail Oxatriquinane.svg?width=300.
- Oxatriquinane wikiPageID "20068758".
- Oxatriquinane wikiPageRevisionID "602112436".
- Oxatriquinane hasPhotoCollection Oxatriquinane.
- Oxatriquinane imagefilel "Oxatriquinane.svg".
- Oxatriquinane imagefiler "Oxatriquinane.png".
- Oxatriquinane iupacname "-Octahydro-1H-2a1-oxacyclopenta[cd]pentalen-2a1-ium".
- Oxatriquinane verifiedrevid "408295395".
- Oxatriquinane subject Category:Oxycations.
- Oxatriquinane subject Category:Oxygen_heterocycles.
- Oxatriquinane type Abstraction100002137.
- Oxatriquinane type Chemical114806838.
- Oxatriquinane type Compound114818238.
- Oxatriquinane type HeterocyclicCompound115025397.
- Oxatriquinane type Material114580897.
- Oxatriquinane type Matter100020827.
- Oxatriquinane type OxygenHeterocycles.
- Oxatriquinane type Part113809207.
- Oxatriquinane type PhysicalEntity100001930.
- Oxatriquinane type Relation100031921.
- Oxatriquinane type Substance100019613.
- Oxatriquinane type ChemicalCompound.
- Oxatriquinane type ChemicalSubstance.
- Oxatriquinane type ChemicalObject.
- Oxatriquinane type Thing.
- Oxatriquinane comment "Oxatriquinane is an alkyl oxonium ion with formula C9H15O+, remarkable for being stable in aqueous solution. It has a cyclononane backbone, with the trivalent oxygen connected to carbons 1,4, and 7, forming three fused pentagonal cycles.Oxonium ions normally are strong alkylating agents and are only observed in solution as reactive intermediates or under extreme conditions.".
- Oxatriquinane label "Oxatriquinane".
- Oxatriquinane sameAs m.04ydyc2.
- Oxatriquinane sameAs Q7115118.
- Oxatriquinane sameAs Q7115118.
- Oxatriquinane sameAs Oxatriquinane.
- Oxatriquinane wasDerivedFrom Oxatriquinane?oldid=602112436.
- Oxatriquinane depiction Oxatriquinane.svg.
- Oxatriquinane isPrimaryTopicOf Oxatriquinane.
