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- Phosphole abstract "Phosphole is the organic compound with the chemical formula C4H4PH; it is the phosphorus analog of pyrrole. The term phosphole also refers to substituted derivatives of the parent heterocycle. These compounds are of theoretical interest but also serve as ligands for transition metals and as precursors to more complex organophosphorus compounds.The first phosphole, pentaphenylphosphole, was reported in 1953, and the parent phosphole itself was first described in 1987. The usual route to phospholes is via the McCormack reaction, involving the addition of a 1,3-diene to a phosphonous chloride followed by dehydrohalogenation. Phenylphospholes can be prepared via zirconacyclopentadienes by reaction with PhPCl2.Unlike the related 5-membered heterocycles pyrrole, thiophene, and furan, the aromaticity of phospholes is diminished, reflecting the reluctance of phosphorus to delocalize its lone pair. For example, phospholes undergo Diels-Alder reactions with electrophilic alkynes.Phospholes↑ ↑ ↑ ↑".
- Phosphole iupacName "1H-Phosphole".
- Phosphole thumbnail UnsubstitutedPhosphole.png?width=300.
- Phosphole wikiPageID "4548139".
- Phosphole wikiPageRevisionID "602112837".
- Phosphole hasPhotoCollection Phosphole.
- Phosphole imagefilel "UnsubstitutedPhosphole.png".
- Phosphole imagefiler "Phosphole-3D-vdW.png".
- Phosphole iupacname "1".
- Phosphole subject Category:Phosphorus_heterocycles.
- Phosphole type Abstraction100002137.
- Phosphole type Chemical114806838.
- Phosphole type Compound114818238.
- Phosphole type HeterocyclicCompound115025397.
- Phosphole type Material114580897.
- Phosphole type Matter100020827.
- Phosphole type Part113809207.
- Phosphole type PhosphorusHeterocycles.
- Phosphole type PhysicalEntity100001930.
- Phosphole type Relation100031921.
- Phosphole type Substance100019613.
- Phosphole type ChemicalCompound.
- Phosphole type ChemicalSubstance.
- Phosphole type ChemicalObject.
- Phosphole type Thing.
- Phosphole comment "Phosphole is the organic compound with the chemical formula C4H4PH; it is the phosphorus analog of pyrrole. The term phosphole also refers to substituted derivatives of the parent heterocycle. These compounds are of theoretical interest but also serve as ligands for transition metals and as precursors to more complex organophosphorus compounds.The first phosphole, pentaphenylphosphole, was reported in 1953, and the parent phosphole itself was first described in 1987.".
- Phosphole label "Fosfol".
- Phosphole label "Fosfolo".
- Phosphole label "Phosphol".
- Phosphole label "Phosphole".
- Phosphole label "Phosphole".
- Phosphole label "ホスホール".
- Phosphole sameAs Phosphol.
- Phosphole sameAs Phosphole.
- Phosphole sameAs Fosfolo.
- Phosphole sameAs ホスホール.
- Phosphole sameAs Fosfol.
- Phosphole sameAs m.0c89nf.
- Phosphole sameAs Q419073.
- Phosphole sameAs Q419073.
- Phosphole sameAs Phosphole.
- Phosphole wasDerivedFrom Phosphole?oldid=602112837.
- Phosphole depiction UnsubstitutedPhosphole.png.
- Phosphole isPrimaryTopicOf Phosphole.