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- Sakurai_reaction abstract "The Sakurai reaction (also known as the Hosomi–Sakurai reaction) is the chemical reaction of carbon electrophiles (such as a ketone shown here) with allylic silanes catalyzed by strong Lewis acids. It is named after the chemists Akira Hosomi and Hideki Sakurai.Lewis acid activation is essential for complete reaction. Strong Lewis acids such as titanium tetrachloride, boron trifluoride, tin tetrachloride, and AlCl(Et)2 are all effective in promoting the Hosomi reaction. The reaction is a type of electrophilic allyl shift with formation of an intermediate beta-silyl carbocation. Driving force is the stabilization of said carbocation by the beta-silicon effect.".
- Sakurai_reaction thumbnail Sakurai_Reaction_Scheme.png?width=300.
- Sakurai_reaction wikiPageExternalLink ksntsuku70.
- Sakurai_reaction wikiPageExternalLink hosomi-sakurai-reaction.shtm.
- Sakurai_reaction wikiPageID "3934577".
- Sakurai_reaction wikiPageRevisionID "598078607".
- Sakurai_reaction hasPhotoCollection Sakurai_reaction.
- Sakurai_reaction subject Category:Addition_reactions.
- Sakurai_reaction subject Category:Carbon-carbon_bond_forming_reactions.
- Sakurai_reaction subject Category:Name_reactions.
- Sakurai_reaction type AdditionReaction113427356.
- Sakurai_reaction type AdditionReactions.
- Sakurai_reaction type ChemicalProcess113446390.
- Sakurai_reaction type ChemicalReaction113447361.
- Sakurai_reaction type NameReactions.
- Sakurai_reaction type NaturalProcess113518963.
- Sakurai_reaction type PhysicalEntity100001930.
- Sakurai_reaction type Process100029677.
- Sakurai_reaction comment "The Sakurai reaction (also known as the Hosomi–Sakurai reaction) is the chemical reaction of carbon electrophiles (such as a ketone shown here) with allylic silanes catalyzed by strong Lewis acids. It is named after the chemists Akira Hosomi and Hideki Sakurai.Lewis acid activation is essential for complete reaction. Strong Lewis acids such as titanium tetrachloride, boron trifluoride, tin tetrachloride, and AlCl(Et)2 are all effective in promoting the Hosomi reaction.".
- Sakurai_reaction label "Hosomi-Sakurai-Reaktion".
- Sakurai_reaction label "Reacción de Sakurai".
- Sakurai_reaction label "Sakurai reaction".
- Sakurai_reaction label "Sakurai-allylering".
- Sakurai_reaction label "樱井反应".
- Sakurai_reaction label "細見・櫻井反応".
- Sakurai_reaction sameAs Hosomi-Sakurai-Reaktion.
- Sakurai_reaction sameAs Reacción_de_Sakurai.
- Sakurai_reaction sameAs 細見・櫻井反応.
- Sakurai_reaction sameAs Sakurai-allylering.
- Sakurai_reaction sameAs m.0b7hsv.
- Sakurai_reaction sameAs Q903031.
- Sakurai_reaction sameAs Q903031.
- Sakurai_reaction sameAs Sakurai_reaction.
- Sakurai_reaction wasDerivedFrom Sakurai_reaction?oldid=598078607.
- Sakurai_reaction depiction Sakurai_Reaction_Scheme.png.
- Sakurai_reaction isPrimaryTopicOf Sakurai_reaction.
