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- Sec-Butyllithium abstract "sec-Butyllithium is an organometallic compound with the formula CH3CHLiCH2CH3, abbreviated sec-BuLi or s-BuLi. This chiral organolithium reagent is used as a source of sec-butyl carbanion in organic synthesis.sec-BuLi can be prepared by the reaction of sec-butyl halides with lithium metal: The carbon-lithium bond is highly polar, rendering the carbon basic, as in other organolithium reagents. Sec-butyllithium is more basic than the primary organolithium reagent, n-butyllithium. It is also more sterically hindered, though it is still useful for syntheses. sec-BuLi is employed for deprotonations of particularly weak carbon acids where the more conventional reagent n-BuLi is unsatisfactory. It is, however, so basic that its use requires greater care than for n-BuLi. For example diethyl ether is attacked by sec-BuLi at room temperature in minutes, whereas ether solutions of n-BuLi are stable. Many transformations involving sec-butyllithium are similar to those involving other organolithium reagents. For example, sec-BuLi react with carbonyl compounds and esters to form alcohols. With copper(I) iodide sec-BuLi forms lithium di-sec-butylcuprates. The first two reactions can also be accomplished by using sec-butylmagnesium bromide, a Grignard reagent; in fact, the latter is the typical reagent for this purpose.".
- Sec-Butyllithium iupacName "sec-Butyllithium".
- Sec-Butyllithium thumbnail Sec-butyllithium-monomer-2D-skeletal.png?width=300.
- Sec-Butyllithium wikiPageExternalLink 00217.htm.
- Sec-Butyllithium wikiPageID "6847430".
- Sec-Butyllithium wikiPageRevisionID "561727877".
- Sec-Butyllithium hasPhotoCollection Sec-Butyllithium.
- Sec-Butyllithium imagefile "Sec-butyllithium-2D-skeletal.png".
- Sec-Butyllithium imagefile "Sec-butyllithium-monomer-2D-skeletal.png".
- Sec-Butyllithium imagename "Skeletal formula of sec-butyllithium".
- Sec-Butyllithium imagename "Skeletal formula of tetrameric sec-butyllithium".
- Sec-Butyllithium imagesize "121".
- Sec-Butyllithium iupacname "sec-Butyllithium".
- Sec-Butyllithium name "sec-Butyllithium".
- Sec-Butyllithium systematicname "Butan-2-yllithium".
- Sec-Butyllithium verifiedrevid "464388187".
- Sec-Butyllithium subject Category:Organolithium_compounds.
- Sec-Butyllithium type Abstraction100002137.
- Sec-Butyllithium type Cognition100023271.
- Sec-Butyllithium type Compound105870180.
- Sec-Butyllithium type Concept105835747.
- Sec-Butyllithium type Content105809192.
- Sec-Butyllithium type Idea105833840.
- Sec-Butyllithium type OrganolithiumCompounds.
- Sec-Butyllithium type PsychologicalFeature100023100.
- Sec-Butyllithium type Whole105869584.
- Sec-Butyllithium type ChemicalCompound.
- Sec-Butyllithium type ChemicalSubstance.
- Sec-Butyllithium type ChemicalSubstanceType.
- Sec-Butyllithium type ChemicalObject.
- Sec-Butyllithium type Thing.
- Sec-Butyllithium comment "sec-Butyllithium is an organometallic compound with the formula CH3CHLiCH2CH3, abbreviated sec-BuLi or s-BuLi. This chiral organolithium reagent is used as a source of sec-butyl carbanion in organic synthesis.sec-BuLi can be prepared by the reaction of sec-butyl halides with lithium metal: The carbon-lithium bond is highly polar, rendering the carbon basic, as in other organolithium reagents. Sec-butyllithium is more basic than the primary organolithium reagent, n-butyllithium.".
- Sec-Butyllithium label "S-Butyllithium".
- Sec-Butyllithium label "Sec-Butyllithium".
- Sec-Butyllithium label "Sec-Butyllithium".
- Sec-Butyllithium label "Sec-butyllithium".
- Sec-Butyllithium label "Sec-ブチルリチウム".
- Sec-Butyllithium sameAs Sec-Butyllithium.
- Sec-Butyllithium sameAs Sec-butyllithium.
- Sec-Butyllithium sameAs Sec-ブチルリチウム.
- Sec-Butyllithium sameAs S-Butyllithium.
- Sec-Butyllithium sameAs m.0gscj9.
- Sec-Butyllithium sameAs Q220108.
- Sec-Butyllithium sameAs Q220108.
- Sec-Butyllithium sameAs Sec-Butyllithium.
- Sec-Butyllithium wasDerivedFrom Sec-Butyllithium?oldid=561727877.
- Sec-Butyllithium depiction Sec-butyllithium-monomer-2D-skeletal.png.
- Sec-Butyllithium isPrimaryTopicOf Sec-Butyllithium.
- Sec-Butyllithium name "sec-Butyllithium".
