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- Steric_factor abstract "Steric factor, P is a term used in collision theory.It is defined as the ratio between the experimental value of the rate constant and the one predicted by collision theory. It can also be defined as the ratio between the preexponential factor and the collision frequency, and it is most often less than unity. Physically, the steric factor can be interpreted as the ratio of the cross section for reactive collisions to the total collision cross section.Usually, the more complex the reactant molecules, the lower the steric factors. Nevertheless, some reactions exhibit steric factors greater than unity: the harpoon reactions, which involve atoms that exchange electrons, producing ions. The deviation from unity can have different causes: the molecules are not spherical, so different geometries are possible; not all the kinetic energy is delivered into the right spot; the presence of a solvent (when applied to solutions)...When collision theory applied to reactions in solution the solvent cage has an effect on the reactant molecules, as several collisions can take place in a single encounter, which leads to predicted preexponential factors being too large. ρ values greater than unity can be attributed to favorable entropic contributions.Usually there is no simple way to accurately estimate steric factors without performing trajectory or scattering calculations.".
- Steric_factor wikiPageID "1604816".
- Steric_factor wikiPageRevisionID "603244198".
- Steric_factor hasPhotoCollection Steric_factor.
- Steric_factor subject Category:Chemical_kinetics.
- Steric_factor subject Category:Physical_chemistry.
- Steric_factor comment "Steric factor, P is a term used in collision theory.It is defined as the ratio between the experimental value of the rate constant and the one predicted by collision theory. It can also be defined as the ratio between the preexponential factor and the collision frequency, and it is most often less than unity.".
- Steric_factor label "Fattore sterico".
- Steric_factor label "Steric factor".
- Steric_factor sameAs Fattore_sterico.
- Steric_factor sameAs m.025rxlw.
- Steric_factor sameAs Q3740209.
- Steric_factor sameAs Q3740209.
- Steric_factor wasDerivedFrom Steric_factor?oldid=603244198.
- Steric_factor isPrimaryTopicOf Steric_factor.