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- Tetrapropylammonium_perruthenate abstract "Tetrapropylammonium perruthenate (TPAP or TPAPR) is the chemical compound described by the formula N(C3H7)4RuO4. Sometimes known as the Ley–Griffith reagent, this ruthenium compound is used as a reagent in organic synthesis. This salt consists of the tetrapropylammonium cation and the perruthenate, RuO4− anion. Ruthenium tetroxide is a highly aggressive oxidant, but its one-electron reduced derivative is a mild oxidizing agent for the conversion of alcohols to aldehydes. This oxidizing agent can also be used to oxidize primary alcohols all the way to the carboxylic acid. Use of a higher catalyst loading, larger amount of the co-oxidant, and addition of two equivalents of water. In this situation, the aldehyde reacts with water to form the geminal-diol hydrate, which is then oxidized again.The oxidation generates water that can be removed by adding molecular sieves. TPAP is expensive, but it can be used in catalytic amounts. The catalytic cycle is maintained by adding a stoichiometric amount of a co-oxidant such as N-methylmorpholine N-oxide or molecular oxygen.".
- Tetrapropylammonium_perruthenate iupacName "Tetrapropylammonium perruthenate".
- Tetrapropylammonium_perruthenate thumbnail TPAP.png?width=300.
- Tetrapropylammonium_perruthenate wikiPageID "2878201".
- Tetrapropylammonium_perruthenate wikiPageRevisionID "599931256".
- Tetrapropylammonium_perruthenate hasPhotoCollection Tetrapropylammonium_perruthenate.
- Tetrapropylammonium_perruthenate imagefile "TPAP.png".
- Tetrapropylammonium_perruthenate imagesize "200".
- Tetrapropylammonium_perruthenate iupacname "Tetrapropylammonium perruthenate".
- Tetrapropylammonium_perruthenate verifiedrevid "428796470".
- Tetrapropylammonium_perruthenate watchedfields "changed".
- Tetrapropylammonium_perruthenate subject Category:Oxidizing_agents.
- Tetrapropylammonium_perruthenate subject Category:Quaternary_ammonium_compounds.
- Tetrapropylammonium_perruthenate subject Category:Ruthenium_compounds.
- Tetrapropylammonium_perruthenate type Abstraction100002137.
- Tetrapropylammonium_perruthenate type Chemical114806838.
- Tetrapropylammonium_perruthenate type Cognition100023271.
- Tetrapropylammonium_perruthenate type Compound105870180.
- Tetrapropylammonium_perruthenate type Compound114818238.
- Tetrapropylammonium_perruthenate type Concept105835747.
- Tetrapropylammonium_perruthenate type Content105809192.
- Tetrapropylammonium_perruthenate type Idea105833840.
- Tetrapropylammonium_perruthenate type Material114580897.
- Tetrapropylammonium_perruthenate type Matter100020827.
- Tetrapropylammonium_perruthenate type OrganicCompound114727670.
- Tetrapropylammonium_perruthenate type Part113809207.
- Tetrapropylammonium_perruthenate type PhysicalEntity100001930.
- Tetrapropylammonium_perruthenate type PsychologicalFeature100023100.
- Tetrapropylammonium_perruthenate type QuaternaryAmmoniumCompound114691231.
- Tetrapropylammonium_perruthenate type QuaternaryAmmoniumCompounds.
- Tetrapropylammonium_perruthenate type Relation100031921.
- Tetrapropylammonium_perruthenate type RutheniumCompounds.
- Tetrapropylammonium_perruthenate type Substance100019613.
- Tetrapropylammonium_perruthenate type Whole105869584.
- Tetrapropylammonium_perruthenate type ChemicalCompound.
- Tetrapropylammonium_perruthenate type ChemicalSubstance.
- Tetrapropylammonium_perruthenate type ChemicalSubstanceType.
- Tetrapropylammonium_perruthenate type ChemicalObject.
- Tetrapropylammonium_perruthenate type Thing.
- Tetrapropylammonium_perruthenate comment "Tetrapropylammonium perruthenate (TPAP or TPAPR) is the chemical compound described by the formula N(C3H7)4RuO4. Sometimes known as the Ley–Griffith reagent, this ruthenium compound is used as a reagent in organic synthesis. This salt consists of the tetrapropylammonium cation and the perruthenate, RuO4− anion. Ruthenium tetroxide is a highly aggressive oxidant, but its one-electron reduced derivative is a mild oxidizing agent for the conversion of alcohols to aldehydes.".
- Tetrapropylammonium_perruthenate label "Perruthénate de tétrapropylammonium".
- Tetrapropylammonium_perruthenate label "Tetrapropylammonium perruthenate".
- Tetrapropylammonium_perruthenate label "Tetrapropylammoniumperruthenat".
- Tetrapropylammonium_perruthenate label "فوق روثينات رباعي بروبيل الأمونيوم".
- Tetrapropylammonium_perruthenate label "過ルテニウム酸テトラプロピルアンモニウム".
- Tetrapropylammonium_perruthenate sameAs Tetrapropylammoniumperruthenat.
- Tetrapropylammonium_perruthenate sameAs Perruthénate_de_tétrapropylammonium.
- Tetrapropylammonium_perruthenate sameAs 過ルテニウム酸テトラプロピルアンモニウム.
- Tetrapropylammonium_perruthenate sameAs m.088mm2.
- Tetrapropylammonium_perruthenate sameAs Q412706.
- Tetrapropylammonium_perruthenate sameAs Q412706.
- Tetrapropylammonium_perruthenate sameAs Tetrapropylammonium_perruthenate.
- Tetrapropylammonium_perruthenate wasDerivedFrom Tetrapropylammonium_perruthenate?oldid=599931256.
- Tetrapropylammonium_perruthenate depiction TPAP.png.
- Tetrapropylammonium_perruthenate isPrimaryTopicOf Tetrapropylammonium_perruthenate.
