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catalog abstract ""This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up to, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances."--Jacket.".
catalog contributor b11427406.
catalog created "1999.".
catalog date "1999".
catalog date "1999.".
catalog dateCopyrighted "1999.".
catalog description ""This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up to, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances."--Jacket.".
catalog description "Includes bibliographical references and index.".
catalog description "Polypyrazolylborates--Scorpionates -- The Abbreviation System for Scorpionate Ligands -- Comparison of the Tp and Cp Ligands -- Historical Development -- Reviews -- Synthesis of Scorpionate Ligands -- List of Known Scorpionate Ligands -- Analogs of Scorpionate Ligands -- Homoscorpionates--First Generation -- Group 1: H, Li, Na, K, Rb and Cs -- Group 2: Be, Mg, Ca, Sr, Ba -- Group 3: Sc, Y -- Group 4: Ti, Zr, Hf -- Group 5: V, Nb, Ta -- Group 6: Cr, Mo, W -- Group 7: Mn, Tc, Re -- Group 8: Fe, R, Os -- Group 9: Co, Rh, Ir -- Group 10: Ni, Pd, Pt -- Group 11: Cu, Ag, Au -- Group 12: Zn, Cd, Hg -- Group 13: B, Al, Ga, In, Tl -- Group 14: C, Si, Ge, Sn, Pb -- Group 15: N, P, As, Sb, Bi -- Lanthanides -- Actinides -- Homoscorpionates--Second Generation -- Regiochemistry in Ligand Synthesis -- Quantification of Steric Effects in Tp[superscript x] Ligands -- Ligand Rearrangments -- Individual Ligands -- B-substituted Ligands, RTp[superscript x] (R [not equal] pz[superscript x]) -- 3-Monosubstituted Ligands, Tp[superscript R] -- 4-Monosubstituted Ligands, Tp[superscript 4R] -- 5-Monosubstituted Ligands, Tp[superscript 5R] -- C-Disubstituted Ligands -- 3,4-Disubstituted Ligands -- 3,5-Disubstituted Ligands of Type Tp[superscript R2] -- 3,5-Disubstituted Ligands of Type Tp[superscript R, R'] -- 4,5-Disubstituted Ligands -- Trisubstituted Ligands -- Heteroscorpionates, RR'Bp[superscript x] -- Specific Ligands -- Bp[superscript x] Ligands -- R[subscript 2]Bp[superscript x] Ligands -- Ligands R(R'Z)Bp[superscript x] -- Specific Ligands.".
catalog extent "282 p. : b. ill ;".
catalog identifier "1860941729".
catalog issued "1999".
catalog issued "1999.".
catalog language "eng".
catalog publisher "River Edge, NJ : Imperial College Press,".
catalog subject "541.2/242 21".
catalog subject "QD474 .T76 1999".
catalog subject "Scorpionates.".
catalog tableOfContents "Polypyrazolylborates--Scorpionates -- The Abbreviation System for Scorpionate Ligands -- Comparison of the Tp and Cp Ligands -- Historical Development -- Reviews -- Synthesis of Scorpionate Ligands -- List of Known Scorpionate Ligands -- Analogs of Scorpionate Ligands -- Homoscorpionates--First Generation -- Group 1: H, Li, Na, K, Rb and Cs -- Group 2: Be, Mg, Ca, Sr, Ba -- Group 3: Sc, Y -- Group 4: Ti, Zr, Hf -- Group 5: V, Nb, Ta -- Group 6: Cr, Mo, W -- Group 7: Mn, Tc, Re -- Group 8: Fe, R, Os -- Group 9: Co, Rh, Ir -- Group 10: Ni, Pd, Pt -- Group 11: Cu, Ag, Au -- Group 12: Zn, Cd, Hg -- Group 13: B, Al, Ga, In, Tl -- Group 14: C, Si, Ge, Sn, Pb -- Group 15: N, P, As, Sb, Bi -- Lanthanides -- Actinides -- Homoscorpionates--Second Generation -- Regiochemistry in Ligand Synthesis -- Quantification of Steric Effects in Tp[superscript x] Ligands -- Ligand Rearrangments -- Individual Ligands -- B-substituted Ligands, RTp[superscript x] (R [not equal] pz[superscript x]) -- 3-Monosubstituted Ligands, Tp[superscript R] -- 4-Monosubstituted Ligands, Tp[superscript 4R] -- 5-Monosubstituted Ligands, Tp[superscript 5R] -- C-Disubstituted Ligands -- 3,4-Disubstituted Ligands -- 3,5-Disubstituted Ligands of Type Tp[superscript R2] -- 3,5-Disubstituted Ligands of Type Tp[superscript R, R'] -- 4,5-Disubstituted Ligands -- Trisubstituted Ligands -- Heteroscorpionates, RR'Bp[superscript x] -- Specific Ligands -- Bp[superscript x] Ligands -- R[subscript 2]Bp[superscript x] Ligands -- Ligands R(R'Z)Bp[superscript x] -- Specific Ligands.".
catalog title "Scorpionates : the coordination chemistry of polypyrazolborate ligands / Swiatoslaw Trofimenko.".
catalog type "text".