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00067814 contributor B63625.
00067814 created "2002.".
00067814 date "2002".
00067814 date "2002.".
00067814 dateCopyrighted "2002.".
00067814 description "Includes bibliographical references and index.".
00067814 description "Machine generated contents note: 1 Reactive Separation Processes -- William A. Leet and Santi Kulprathipanja -- 1.1 Introduction -- 1.2 Advantages and Disadvantages -- 1.2.1 Advantages -- 1.2.2 Disadvantages -- 1.3 Applications Topics -- 1.4 Conclusions -- References -- 2 Reactive Distillation -- Gavin P. Towler and Stanley J. Frey -- 2.1 Introduction -- 2.2 Industrial Applications -- 2.2.1 Esterification -- 2.2.2 Etherification -- 2.3 Theory -- 2.3.1 Equilibrium Behavior -- 2.3.2 Kinetically Limited Behavior -- 2.4 Modeling and Design -- 2.4.1 Equilibrium Modeling -- 2.4.2 Rate-Limited Modeling -- 2.5 Practical Design Considerations -- 2.5.1 Installation, Containment, and Removal of the -- Catalyst -- 2.5.2 Design for Good Reactive Phase Contact with the -- Catalyst -- 2.5.3 Design for Liquid-Vapor Contacting Through -- the Reactive Zone -- 2.5.4 Design for Proper Pressure Drop Through the -- Reactive Zone -- 2.5.5 Design for Proper Liquid Hold-Up -- 2.5.6 Design for Catalyst Deactivation -- 2.6 Commercially Proven Equipment Technology -- 2.6.1 Chemical Research & Licensing (CR&L) Catalyst -- Bales -- 2.6.2 Koch-Glitsch, Inc. Catalyst-Containing Structured -- Packing -- 2.6.3 Eastman Chemical High Liquid Hold-up Trays -- 2.6.4 Other Leading Reactive Distillation Equipment -- Concepts -- 2.7 Conclusions -- Symbols -- References -- 3 Extraction with Reaction -- Vincent Van Brunt and Jeffrey S. Kanel -- 3.1 Introduction -- 3.2 Hydrometallurgical Separations -- 3.3 Homogeneous Reactions: Organic Separations -- 3.3.1 Introduction -- 3.3.2 Hydrolysis -- 3.3.3 Saponification -- 3.3.4 Esterification -- 3.3.5 Transesterification -- 3.3.6 Polycarbonates -- 3.3.7 Nitration -- 3.3.8 UOP HF Alkylation Technology -- 3.3.9 UOP HF Detergent Alkylate Process -- 3.3.10 Oxidation -- 3.3.11 Oximation -- 3.3.12 Shell Higher Olefin Process (SHOP) -- 3.3.13 Hydroformylation -- 3.3.14 Modifiers, Phase Transfer Catalysts, and Surfactants -- 3.3.15 Dense Gas and Ionic Fluid Applications -- 3.4 Conclusions -- References -- 4 Absorption with Reaction -- Jerry H. Meldon -- 4.1 Introduction -- 4.2 Local Mass Transfer Models -- 4.3 Mass Transfer with Chemical Reaction -- 4.3.1 Irreversible Reaction -- 4.3.2 Reversible Reaction -- 4.3.3 Perturbation Methods -- 4.4 Simultaneous Absorption of Carbon Dioxide and -- Hydrogen Sulfide in Alkaline Solutions -- 4.5 Conclusions -- Symbols -- References -- 5 Adsorption with Reaction -- Robert W. Carr and Hemant W. Dandekar -- 5.1 Introduction -- 5.1.1 Applicability -- 5.1.2 Attributes -- 5.2 Reactor Types -- 5.2.1 Rotating Cylindrical Annulus Chromatographic -- Reactors -- 5.2.2 Countercurrent Moving-Bed Chromatographic -- Reactors -- 5.2.3 Simulated Countercurrent Moving-Bed -- Chromatographic Reactors -- 5.2.4 Pressure-Swing Adsorption Reactors -- 5.2.5 The Trickle-Bed Reactor -- 5.3 Issues in Adsorbent/Catalyst and Reactor Design -- 5.3.1 Adsorption Issues -- 5.3.2 Reaction Issues -- 5.3.3 Particle Design -- 5.4 Applications -- 5.4.1 Equilibrium-Limited Reactions -- 5.4.2 Selectivity-Limited Reactions -- 5.5 Process Evaluation -- 5.5.1 Impact on Process Flowsheet -- 5.5.2 Economic Impact -- 5.6 Conclusions -- Symbols -- References -- 6 Reactive Membrane Separation -- Jose G. Sanchez Marcano and Theodore T. Tsotsis -- 6.1 Introduction -- 6.2 Catalytic Reactive Separation Processes -- 6.2.1 Dehydrogenation Reactions -- 6.2.2 Hydrogenation Reactions -- 6.2.3 Oxidation Reactions -- 6.2.4 Other High-Temperature Applications -- 6.2.5 Economic Considerations -- 6.2.6 Emerging Applications -- 6.3 Pervaporation Membrane Reactors -- 6.4 Membrane-Based Reactive Separations for Biological -- Processes -- 6.5 Environmental Applications of Membrane Bioreactors -- 6.6 Modeling of Membrane-Based Reactive Separation -- Processes -- 6.7 Conclusions -- Symbols -- References -- 7 Reactive Crystallization -- Vaibhav V. Kelkar, Ketan D. Samant, and Ka M. Ng -- 7.1 Introduction -- 7.2 Solid-Liquid Phase Diagrams with Reactions -- 7.2.1 Generation of Phase Diagrams -- 7.2.2 Example Phase Diagrams -- 7.2.3 Representation of High-Dimensional Phase -- Diagrams -- 7.2.4 Process Synthesis Based on Phase Diagrams -- 7.3 Crystallization Kinetics -- 7.3.1 Kinetics of Nucleation -- 7.3.2 Kinetics of Crystal Growth -- 7.4 The Population Balance -- 7.5 Generic Model for a Reactive Crystallizer -- 7.6 Mixing in Reactive Crystallizers -- 7.6.1 Experimental Studies -- 7.6.2 Modeling of Turbulent Mixing in Reactive -- Crystallizers -- 7.6.3 Operating Regimes -- 7.6.4 Effect of Operating Conditions on Crystal -- Attributes -- 7.6.5 Choice of Operating Regimes -- 7.7 Conclusions -- Symbols -- References.".
00067814 extent "xvi, 251 p. :".
00067814 identifier "1560328258 (alk. paper)".
00067814 identifier 00067814-d.html.
00067814 identifier 00067814.html.
00067814 issued "2002".
00067814 issued "2002.".
00067814 language "eng".
00067814 publisher "New York : Taylor & Francis,".
00067814 subject "660/.2842 21".
00067814 subject "Separation (Technology)".
00067814 subject "TP156.S45 R39 2002".
00067814 tableOfContents "Machine generated contents note: 1 Reactive Separation Processes -- William A. Leet and Santi Kulprathipanja -- 1.1 Introduction -- 1.2 Advantages and Disadvantages -- 1.2.1 Advantages -- 1.2.2 Disadvantages -- 1.3 Applications Topics -- 1.4 Conclusions -- References -- 2 Reactive Distillation -- Gavin P. Towler and Stanley J. Frey -- 2.1 Introduction -- 2.2 Industrial Applications -- 2.2.1 Esterification -- 2.2.2 Etherification -- 2.3 Theory -- 2.3.1 Equilibrium Behavior -- 2.3.2 Kinetically Limited Behavior -- 2.4 Modeling and Design -- 2.4.1 Equilibrium Modeling -- 2.4.2 Rate-Limited Modeling -- 2.5 Practical Design Considerations -- 2.5.1 Installation, Containment, and Removal of the -- Catalyst -- 2.5.2 Design for Good Reactive Phase Contact with the -- Catalyst -- 2.5.3 Design for Liquid-Vapor Contacting Through -- the Reactive Zone -- 2.5.4 Design for Proper Pressure Drop Through the -- Reactive Zone -- 2.5.5 Design for Proper Liquid Hold-Up -- 2.5.6 Design for Catalyst Deactivation -- 2.6 Commercially Proven Equipment Technology -- 2.6.1 Chemical Research & Licensing (CR&L) Catalyst -- Bales -- 2.6.2 Koch-Glitsch, Inc. Catalyst-Containing Structured -- Packing -- 2.6.3 Eastman Chemical High Liquid Hold-up Trays -- 2.6.4 Other Leading Reactive Distillation Equipment -- Concepts -- 2.7 Conclusions -- Symbols -- References -- 3 Extraction with Reaction -- Vincent Van Brunt and Jeffrey S. Kanel -- 3.1 Introduction -- 3.2 Hydrometallurgical Separations -- 3.3 Homogeneous Reactions: Organic Separations -- 3.3.1 Introduction -- 3.3.2 Hydrolysis -- 3.3.3 Saponification -- 3.3.4 Esterification -- 3.3.5 Transesterification -- 3.3.6 Polycarbonates -- 3.3.7 Nitration -- 3.3.8 UOP HF Alkylation Technology -- 3.3.9 UOP HF Detergent Alkylate Process -- 3.3.10 Oxidation -- 3.3.11 Oximation -- 3.3.12 Shell Higher Olefin Process (SHOP) -- 3.3.13 Hydroformylation -- 3.3.14 Modifiers, Phase Transfer Catalysts, and Surfactants -- 3.3.15 Dense Gas and Ionic Fluid Applications -- 3.4 Conclusions -- References -- 4 Absorption with Reaction -- Jerry H. Meldon -- 4.1 Introduction -- 4.2 Local Mass Transfer Models -- 4.3 Mass Transfer with Chemical Reaction -- 4.3.1 Irreversible Reaction -- 4.3.2 Reversible Reaction -- 4.3.3 Perturbation Methods -- 4.4 Simultaneous Absorption of Carbon Dioxide and -- Hydrogen Sulfide in Alkaline Solutions -- 4.5 Conclusions -- Symbols -- References -- 5 Adsorption with Reaction -- Robert W. Carr and Hemant W. Dandekar -- 5.1 Introduction -- 5.1.1 Applicability -- 5.1.2 Attributes -- 5.2 Reactor Types -- 5.2.1 Rotating Cylindrical Annulus Chromatographic -- Reactors -- 5.2.2 Countercurrent Moving-Bed Chromatographic -- Reactors -- 5.2.3 Simulated Countercurrent Moving-Bed -- Chromatographic Reactors -- 5.2.4 Pressure-Swing Adsorption Reactors -- 5.2.5 The Trickle-Bed Reactor -- 5.3 Issues in Adsorbent/Catalyst and Reactor Design -- 5.3.1 Adsorption Issues -- 5.3.2 Reaction Issues -- 5.3.3 Particle Design -- 5.4 Applications -- 5.4.1 Equilibrium-Limited Reactions -- 5.4.2 Selectivity-Limited Reactions -- 5.5 Process Evaluation -- 5.5.1 Impact on Process Flowsheet -- 5.5.2 Economic Impact -- 5.6 Conclusions -- Symbols -- References -- 6 Reactive Membrane Separation -- Jose G. Sanchez Marcano and Theodore T. Tsotsis -- 6.1 Introduction -- 6.2 Catalytic Reactive Separation Processes -- 6.2.1 Dehydrogenation Reactions -- 6.2.2 Hydrogenation Reactions -- 6.2.3 Oxidation Reactions -- 6.2.4 Other High-Temperature Applications -- 6.2.5 Economic Considerations -- 6.2.6 Emerging Applications -- 6.3 Pervaporation Membrane Reactors -- 6.4 Membrane-Based Reactive Separations for Biological -- Processes -- 6.5 Environmental Applications of Membrane Bioreactors -- 6.6 Modeling of Membrane-Based Reactive Separation -- Processes -- 6.7 Conclusions -- Symbols -- References -- 7 Reactive Crystallization -- Vaibhav V. Kelkar, Ketan D. Samant, and Ka M. Ng -- 7.1 Introduction -- 7.2 Solid-Liquid Phase Diagrams with Reactions -- 7.2.1 Generation of Phase Diagrams -- 7.2.2 Example Phase Diagrams -- 7.2.3 Representation of High-Dimensional Phase -- Diagrams -- 7.2.4 Process Synthesis Based on Phase Diagrams -- 7.3 Crystallization Kinetics -- 7.3.1 Kinetics of Nucleation -- 7.3.2 Kinetics of Crystal Growth -- 7.4 The Population Balance -- 7.5 Generic Model for a Reactive Crystallizer -- 7.6 Mixing in Reactive Crystallizers -- 7.6.1 Experimental Studies -- 7.6.2 Modeling of Turbulent Mixing in Reactive -- Crystallizers -- 7.6.3 Operating Regimes -- 7.6.4 Effect of Operating Conditions on Crystal -- Attributes -- 7.6.5 Choice of Operating Regimes -- 7.7 Conclusions -- Symbols -- References.".
00067814 title "Reactive separation processes / edited by Santi Kulprathipanja.".
00067814 type "text".