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- 2012360631 abstract "Catalysis, the basic principle for overcoming the kinetic inhibition of chemical reactions, is fundamental in chemistry. In particular, organometallic catalysis plays an overwhelming role in both research and industry. It opens the way to entirely novel synthetic methods and finds widespread applications ranging from mass-production of every-day polymers to stereocontrolled synthesis of bioactive chemicals used as pharmaceuticals and agrochemicals. The targeted development of improved and novel catalysts demands understanding of the relationships between their structures and catalytic properties. Accordingly, this textbook offers the reader a fundamental understanding of the course of organometallic-catalyzed reactions, starting at the molecular level. The initial chapters explain the principles of catalysis and the elementary steps in organometallic catalysis. The book then explores important organometallic-catalyzed reactions, with a focus on mechanism. Current developments are emphasized throughout. Asymmetric synthesis is covered in depth. FInally, the book examines the catalytic behavior of particular metalloenzymes. A look at nitrogen fixation offers a comparative examination of the three major areas of catalysis--homogeneous, heterogeneous, and enzymatic. In addition to problems, the textbook offers solutions, making the book an invaluable learning tool. It is a must-have for advanced students in chemistry and biochemistry, as well as for inorganic and organic chemists, for those working with organometallics, and for those specializing in catalysis - Source other than Library of Congress.".
- 2012360631 contributor B12533246.
- 2012360631 created "c2012.".
- 2012360631 date "2012".
- 2012360631 date "c2012.".
- 2012360631 dateCopyrighted "c2012.".
- 2012360631 description "Catalysis, the basic principle for overcoming the kinetic inhibition of chemical reactions, is fundamental in chemistry. In particular, organometallic catalysis plays an overwhelming role in both research and industry. It opens the way to entirely novel synthetic methods and finds widespread applications ranging from mass-production of every-day polymers to stereocontrolled synthesis of bioactive chemicals used as pharmaceuticals and agrochemicals. The targeted development of improved and novel catalysts demands understanding of the relationships between their structures and catalytic properties. Accordingly, this textbook offers the reader a fundamental understanding of the course of organometallic-catalyzed reactions, starting at the molecular level. The initial chapters explain the principles of catalysis and the elementary steps in organometallic catalysis. The book then explores important organometallic-catalyzed reactions, with a focus on mechanism. Current developments are emphasized throughout. Asymmetric synthesis is covered in depth. FInally, the book examines the catalytic behavior of particular metalloenzymes. A look at nitrogen fixation offers a comparative examination of the three major areas of catalysis--homogeneous, heterogeneous, and enzymatic. In addition to problems, the textbook offers solutions, making the book an invaluable learning tool. It is a must-have for advanced students in chemistry and biochemistry, as well as for inorganic and organic chemists, for those working with organometallics, and for those specializing in catalysis - Source other than Library of Congress.".
- 2012360631 description "Includes bibliographical references (p. 407-437) and indexes.".
- 2012360631 description "Principles of organometallic catalysis -- Elementary steps in organometallic catalysis -- Hydrogenation of olefins -- Hydroformylation of olefins and Fischer-Tropsch synthesis -- Carbonylation of methanol and water-gas shift reaction -- Metathesis -- Oligomerization olefins --Polymerization of olefins -- C-C linkage of dienes -- C-C coupling reactions -- Hydrocyanation, hydrosilylation, and hydroamination of olefins -- Oxidation of olefins and alkanes -- Nitrogen fixation.".
- 2012360631 extent "xvii, 456 p. :".
- 2012360631 identifier "3527327177 (pbk.)".
- 2012360631 identifier "9783527327171 (hbk.)".
- 2012360631 identifier "9783527327171 (pbk.)".
- 2012360631 issued "2012".
- 2012360631 issued "c2012.".
- 2012360631 language "Translated from the German.".
- 2012360631 language "eng ger".
- 2012360631 language "eng".
- 2012360631 publisher "Weinheim : Wiley-VCH,".
- 2012360631 subject "Catalysis Textbooks.".
- 2012360631 subject "Organometallic chemistry Textbooks.".
- 2012360631 subject "QD505 .S738 2012".
- 2012360631 tableOfContents "Principles of organometallic catalysis -- Elementary steps in organometallic catalysis -- Hydrogenation of olefins -- Hydroformylation of olefins and Fischer-Tropsch synthesis -- Carbonylation of methanol and water-gas shift reaction -- Metathesis -- Oligomerization olefins --Polymerization of olefins -- C-C linkage of dienes -- C-C coupling reactions -- Hydrocyanation, hydrosilylation, and hydroamination of olefins -- Oxidation of olefins and alkanes -- Nitrogen fixation.".
- 2012360631 title "Fundamentals of organometallic catalysis / Dirk Steinborn ; [translator, Alan Frenkel].".
- 2012360631 type "text".