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- aggregation classification "D1".
- aggregation creator person.
- aggregation date "2011".
- aggregation format "application/pdf".
- aggregation hasFormat 1185467.bibtex.
- aggregation hasFormat 1185467.csv.
- aggregation hasFormat 1185467.dc.
- aggregation hasFormat 1185467.didl.
- aggregation hasFormat 1185467.doc.
- aggregation hasFormat 1185467.json.
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- aggregation hasFormat 1185467.mods.
- aggregation hasFormat 1185467.rdf.
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- aggregation hasFormat 1185467.txt.
- aggregation hasFormat 1185467.xls.
- aggregation hasFormat 1185467.yaml.
- aggregation language "eng".
- aggregation publisher "Ghent University. Faculty of Sciences".
- aggregation rights "I have transferred the copyright for this publication to the publisher".
- aggregation subject "Chemistry".
- aggregation title "Highly functionalized star-shaped polymers via click chemistry design".
- aggregation abstract "As only functional star-shaped polymers with low degree of functionalization are known in literature, the initial aim of this research project was to synthesize highly end- and backbone functionalized star-shaped polymer structures by combined Atom Transfer Radical Polymerization (ATRP) and click chemistry. First, the efficiency of both CuAAC and HDA was examined and compared as a technique for the end-group functionalization of star-shaped polymers synthesized via ATRP onto multifunctional initiators. Although this strategy is straightforward, the degree of functionalization is limited by the number of initiating sites of the multifunctional initiators. Therefore, a simple approach based on backbone functionalized star-shaped polymers was developed further on in the research project. Besides, to further increase the industrial applicability of the CuAAC reaction, which is still known as the most popular cycloaddition reaction, the copper catalyst was implanted onto a soluble polymeric support. Traditionally, the catalyst system in CuAAC is removed by one or several post-purification methods from which the catalyst system cannot be recovered. Therefore, we aimed at the development of an air-stable, highly reactive reusable polymer catalyst system for application in CuAAC reactions that works in both water and organic solvents and can be easily regenerated and reused by precipitation or simple extraction exploring its LCST behaviour.".
- aggregation authorList BK1380.
- aggregation aggregates 4335505.
- aggregation isDescribedBy 1185467.
- aggregation similarTo LU-1185467.